一、课题组名称:轻合金与稀散元素分离课题组
二、课题组简介:
轻合金与稀散元素分离课题组聚焦盐湖资源绿色高值利用中的关键科学与技术问题开展研究。围绕盐湖镁锂资源高值化利用,开展以盐湖初级化学品为主要原料的镁、锂轻金属及合金制备工艺及装备开发;围绕盐湖稀散元素资源高效分离和综合利用,开展以吸附为主要技术核心的分离材料、分离工艺及装备开发。团队先后承担包括国家自然科学基金项目、国家科技支撑计划课题、中国科学院相关项目、青海省重大科技专项、青海省杰出青年基金及企业横向委托项目等多项科研课题,在Chemical Engineering Journal、Separationand Purification Technology、Journal of Hazardous Materials、Acs Sustainable Chemistry & Engineering等国际主流SCI刊物上发表学术论文80余篇,申请国家专利60余件,其中授权30余件,目前已有8件专利分别通过转让、许可的方式进行了成果转化。
课题组有固定人员14人,其中研究员5人,副研究员3人,高级实验师1人,博士8人,具有出国进修经历4人。中国科学院特聘研究员1人,中国科学院青年创新促进会成员1人,中国科学院相关人才计划入选者2人,获得中国科学院相关人才计划资助者2人,入选青海省相关人才计划8人,柳大纲优秀青年科技奖获得者2人。课题组外聘柔性合作研究员5人。组内在读博士研究生4人,在读硕士研究生2人,临时聘用技术人员10人。
研究方向一:盐湖镁锂金属、中间合金及应用合金开发
以盐湖氯化镁、氯化锂等为原料,采用熔盐电解法制备镁、锂及相关中间合金,探究熔盐电解行为与机制,研发熔盐电解新工艺,设计制备新型电解槽,开发包括电源系统、电解槽系统、尾气处理系统和自动监测系统在内的整套设备和工程技术。基于盐湖镁锂金属及中间合金,设计研发高强、耐热、耐蚀镁合金及超轻性能的镁锂合金制备工艺,并开展合金成型工艺开发。
研究方向二:吸附材料优化及分离工艺开发
针对盐湖中锂、铷、铯、硼、溴、碘等的分离提取或去除,设计制备新型分离材料,研发分离工艺与装备,系统研究复杂体系中稀散元素分离行为与机制,从静电作用、疏水作用、氢键作用、沉淀作用、络合作用等方面深入研究分离机理,优化分离材料的制备和分离工艺。
三. 课题组组长:
叶秀深,男,1981年生于山东省临清市。现任中国科学院青海盐湖研究所研究员,博士生导师,甘河中试基地主任。1999至2003年在聊城大学化学化工学院获得学士学位。2009年在中国科学院青海盐湖研究所获得博士学位。2016至2017年在韩国延世大学访学研究。目前主要研究领域为轻金属及合金熔盐电解制备工艺及装备研发,铷、铯高效吸附材料与工艺研究。发表研究论文80余篇,申请专利40余件。青海省自然科学与工程技术学科带头人,青海省中青年人才托举工程入选者。
学术兼职:中国有色金属学会冶金物理化学专家委员会委员,中国化工学会无机酸碱盐专家委员会委员,《无机盐工业》青年编委,《盐湖研究》青年编委会副主任委员。
电话(Tel):13897451190
邮编(P.C.):810008
邮箱(Mail):yexs@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
四. 课题组成员:
职工:
博士研究生:
硕士研究生:
五、课题组人才专员:韩文杰
电话(Tel):18202408061;
邮编(P.C.):810008;
邮箱(Mail):hwj@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
六. 招聘信息:
研究方向1:轻金属及合金材料
专业要求:无机化学、冶金物理化学、材料学、材料物理与化学、化学工艺、化学工程、材料科学与工程
学位要求:博士
拟招人数:2人
研究方向2:分离材料与技术
专业要求:无机化学,材料化学,物理化学,化学工艺,材料与化工等相关专业
学位要求:博士
招聘人数:2人
七. 招生信息
本课题组现有中青年研究生导师6名,面向全国公开招考硕士研究生、博士研究生。博士招生专业包括无机化学、物理化学及材料与化工,硕士招生专业包括无机化学、物理化学、化学工艺及材料与化工。课题组同时依托所化学学科博士后流动站面向全国招收博士后研究人员。
欢迎各位青年人才加入“轻合金与稀散元素分离课题组”。
八. 科研项目:
1.项目名称
盐湖关键战略资源的绿色高效分离,中国科学院稳定支持基础研究领域青年团队计划项目,YSBR-039,2022.07-2027.07.
镁稀土合金的绿色制备及应用开发,国家科技支撑计划课题,2012BAE01B04,2012.01-2014.12.
氯化镁在典型无机材料表界面上的结晶及失水行为和机制研究,青海省重点研发与转化计划-科技援青合作专项,2024-QY-203,2024.01-2026.12.
300MPa级高强优质铸造镁合金材料开发,湖南省科技创新计划-重点研发,AC202406121431948951e0,2024.06-2026.06.
以水合氯化物为原料熔盐电解制备镁-稀土中间合金的科学基础与工程化,国家自然科学基金联合基金重点项目,U21A20323,2022.01-2025.12.
钾肥生产中浮选药剂的迁移分布规律、耦合回收、去除技术及机理,国家自然科学基金联合基金重点项目,U20A20150,2021.01-2024.12.
复合分子印迹铷、铯吸附剂的制备及其对柴达木盆地油田水中铷、铯的吸附性能研究,国家自然科学基金面上项目,50972151,2010.01-2012.12.
生物质三维网络碳气凝胶吸附剂对硼酸根及碘离子高选择性吸附及作用机制研究,国家自然科学基金联合基金培育项目,U1507104,2016.01-2018.12.
熔盐电解法制备含镁、锶、锂中间合金新技术基础研究,国家自然科学基金联合基金重点项目-课题,U20A20147,2021.01-2024.12.
盐湖高纯氯化锂的制备及电解氢氧化锂与金属锂的关键科学基础,国家自然科学基金联合基金重点项目-课题,U21A20305,2021.01-2024.12.
以含水氯化物为原料电解制备镁稀土合金工程技术研究与合金应用,中科院西部行动项目,KZCX2-XB3-06,2011.01-2013.12.
铝锶中间合金的熔盐电解制备及高性能铝锶合金研发,青海省企业研究转化与产业化专项,2017-GX-C2,2017.01-2019.12.
镁-锌系中间合金制备新技术及其应用合金开发,青海省重点研发与转化计划,2014-GX-216A,2014.07-2017.06.
年产千吨级金属锂关键技术研发与示范,青海省重点研发与转化计划,2018-GX-121,2018.07-2020.12.
盐湖铷、铯高效富集及分离提取的关键科学基础与技术,青海省杰出青年基金项目,2023-ZJ-940J,2023.01-2025.12.
盐湖氯化镁电解制备镁系中间合金及电解氯气的高值化利用工程化示范,青海盐湖工业股份有限公司重点科技项目,2021.07-2024.06.
盐湖稀有碱金属吸附剂设计制备和高效分离技术研究,青海省自然科学基金创新团队,2020-ZJ-901,2020.01-2022.12.
九. 代表性科研成果:
1.论文及论著
Hu, Y., Hou, Q., Liu, H., Ye, X., One-pot, surfactant-free synthesis of poly(styrene-N,N’-methylenebis (2-propenamide)-acrylic acid) and poly(styrene-N,N’-methylenebis (2-propenamide)-methacrylic acid) microspheres for adsorptive removal of heavy metal ions. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2024, 683, 132651.
Lu, M., Zhang S., Ma, L., Song, Z., Ye, X., Zhang H., Liu, H., Wu, Z., CNT/Nafion functionalized Ti/SnO2-Sb/β-PbO2-CNT/Nafion composite electrode toward highly active and robust degradation of octadecylamine and 4-dodecylmorpholine in real high-salinity system. Chemical Engineering Journal. 2024, 493, 152716.
Luo, Q., Dong, M., Bai, C., Liu, H., Wu, Z., Du, X., Li, J., Huang, X., Green synthesis of polyol functionalized cotton linter polymer adsorbents by the hydrothermal method: Effects of the structure of the ligands for boron anionic species capture. Chemical Engineering Science. 2024, 258, 11957.
Zhou, D., Luo, Q., Nie, G., Dong, M., Du, X., Liu, H., Wu, Z., Li, J., Preparation of high-quality zinc borate flame retardant: The existence mechanism and synergistic coupling separation of chloride ions in zinc borate. Separation and Purification Technology. 2024, 344, 127198.
Zhang S., Ma, L., Liu, W., Dong, M., Pang, Q., Li, Q., Wu, Z., Ye, X., Solvent- and catalyst-free hydrogenation synthesis of lithium hydride at high altitude. Chemical Engineering Science. 2024, 295, 120158.
Song, Z., Zhang H., Ma, L., Lu, M., Wu, C., Liu, Q., Yu, X., Liu, H., Ye, X., Ma, Z., Wu, Z., Basic magnesium sulfate@TiO2 composite for efficient adsorption and photocatalytic degradation of 4-dodecylmorpholine in brine. Scientifc Reports. 2024, 14, 9351.
Wang, Y., Zhang, Q., Li, K., Wang, C., Fang, D., Han, W., Lu, M., Yu, X., Zhang, H., Liu, H., Tan, X., Wu, Z., Efficient selective adsorption of rubidium and cesium from practical brine using a metal−organic framework-based magnetic adsorbent. Langmuir. 2024, 40(18), 9688-9701.
Huang, Y., Chen, J., Liu, H., Wang, Y., Lu, M., Liu, X., Yu, X., Shi, G., Crown ether intercalated graphene oxide membranes for highly efficient sieving of cesium with a large water permeability. Separation and Purification Technology. 2024, 339, 126702.
Wang, Y., Li, K., Ma, L., Fang, D., Lu, M., Ye, X., Liu, H., Zhang, H., Tan, X., Wu, Z., A magnetic adsorbent with metal-organic framework based on ammonium phosphomolybdenum heteropoly tungstate (AWP): selective adsorption of symbolscript and symbolscript from aqueous resources and stripping with ammonium salts. Hydrometallurgy. 2023, 216, 106011.
Wang, Y., Li, K., Fang, D., Ye, X., Liu, H., Tan, X., Li, Q., Li, J., Wu, Z., Ammonium molybdophosphate/metal-organic framework composite as an effective adsorbent for capture of Rb+ and Cs+ from aqueous solution. Journal of Solid State Chemistry. 2022, 306, 122767.
Bai, C., Li, K., Fang, D., Ye, X., Zhang, H., Li, Q., Li, J., Liu, H., Wu, Z., Efficient separation of boron from salt lake brine using a novel flotation agent synthesized from NMDG and 1-bromooctadecane. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2021, 627,127178.
Fang, D., Wang, Y., Liu, H., Zhang, H., Ye, X., Li, Q., Li, J., Wu, Z., Efficient extraction of Rb+ and Cs+ by a precipitation flotation process with ammonium phosphowolframate as precipitant. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2021, 608,125581.
Li, K., Ding, D., Fang, D., Wang, Y., Ye, X., Liu, H., Tan, X., Li, Q., Wu, Z., Hydrothermal deposition of titanate on biomass carbonaceous aerogel to prepare novel biomass adsorbents for Rb+ and Cs+. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2020, 590,124501.
Wang, S., Ye, X., Zhang, H., Qian, Z., Li, Q., Wu, Z., Li, S., Superhydrophobic silane/fluorinated attapulgite@SiO2 composite coatings on magnesium alloy for corrosion protection. Chemistryselect. 2020, 5(33), 10329-10338.
Wang, S., Zhang, H., Qian, Z., Ye, X., Wu, Z., Li, S., A facile strategy for preparing superhydrophobic coating on AZ31 magnesium alloy with stable anticorrosion performance. International Journal of Electrochemical Science. 2020, 15(9), 8397-8407.
Wu, Z., Ye, X., Liu, H., Zhang, H., Liu, Z., Guo, M., Li, Q., Li, J., Interactions between adsorbents and adsorbates in aqueous solutions. Pure and Applied Chemistry. 2020, 92(10), 1655-1662.
Qian, F., Zhao, B., Guo M., Qian, Z., Wu, Z., Liu, Z., Trace doping by fluoride and sulfur to enhance adsorption capacity of manganese oxides for lithium recovery . Materials & Design, 2020, 194, 108867-108878.
Sun, L., Huang, J., Liu, H., Zhang, Y., Ye, X., Zhang, H., Wu, A., Wu, Z., Adsorption of boron by CA@KH-550@EPH@NMDG (CKEN) with biomass carbonaceous aerogels as substrate. Journal of Hazardous Materials. 2018, 358, 10-19.
Sun, L., Zhang, Y., Ye, X., Liu, H., Zhang, H., Wu, A., Wu, Z., Removal of I- from aqueous solutions using a biomass carbonaceous aerogel modified with KH-560. Acs Sustainable Chemistry & Engineering. 2017, 5(9), 7700-7708.
Zhu, Y., Wang, W., Zhang, H., Ye, X., Wu, Z., Wang, A., Fast and high-capacity adsorption of Rb+ and Cs+ onto recyclable magnetic porous spheres. Chemical Engineering Journal. 2017, 327, 982-991.
Zhu, Y., Zhang, H., Wang, W., Ye, X., Wu, Z., Wang, A., Fabrication of a magnetic porous hydrogel sphere for efficient enrichment of Rb+ and Cs+ from aqueous solution. Chemical Engineering Research & Design. 2017, 125, 214-225.
Wang, S., Li, Q., Ye, X., Sun, Q., Wu, Z., Electrolytic preparation of Mg-La alloy in chloride molten salt: effect of electrolyte composition. Rare Metal Materials and Engineering. 2015, 44(7), 1623-1628.
Guo, T., Hu, Y., Gao, X., Ye, X., Liu, H., Wu, Z., Competitive adsorption of Li, Na, K, Rb and Cs ions onto calcium alginate-potassium tetraphenylborate composite adsorbent. Rsc Advances. 2014, 4(46), 24067-24072.
Li, B., Liu, H., Ye, X., Li, S., Wu, Z., Rubidium and cesium ion adsorption by a potassium titanium silicate-calcium alginate composite adsorbent. Separation Science and Technology. 2014, 49(7), 1076-1085.
Gao, X., Hu, Y., Guo, T., Ye, X., Li, Q., Guo, M., Liu, H., Wu, Z., Comparative study of the competitive adsorption of Mg, Ca and Sr ions onto resins. Adsorption Science & Technology. 2013, 31(1), 45-58.
Hu, Y., Guo, T., Ye, X., Li, Q., Guo, M., Liu, H., Wu, Z., Dye adsorption by resins: effect of ionic strength on hydrophobic and electrostatic interactions. Chemical Engineering Journal. 2013, 228, 392-397.
Wang, S., Li, Q., Ye, X., Sun, Q., Wu, Z., Effect of oxide and fluoride addition on electrolytic preparation of Mg-La alloy in chloride molten salt. Transactions of Nonferrous Metals Society of China. 2013, 23(10), 3104-3111.
Zhang, H., Guo, T., Li, Q., Liu, H., Ye, X., Wu, Z., Iodide adsorption onto three organic-inorganic composite adsorbents. Adsorption Science & Technology. 2012, 30(5), 449-460.
Zhang, H., Gao, X., Guo, T., Li, Q., Liu, H., Ye, X., Guo, M., Wu, Z., Adsorption of iodide ions on a calcium alginate-silver chloride composite adsorbent. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2011, 386(1-3), 166-171.
Guo, M., Li, Q., Ye, X., Wu, Z., Magnesium carbonate precipitation under the influence of polyacrylamide. Powder Technology. 2010, 200(1-2), 46-51.
Li, Q., Liu, H., Liu, T., Guo, M., Qing, B., Ye, X., Wu, Z., Strontium and calcium ion adsorption by molecularly imprinted hybrid gel. Chemical Engineering Journal. 2010, 157(2-3), 401-407.
Guo, M., Li, Q., Liu, H., Ye, X., Qing, B., Ge, F., Wu, Z., The exploitation and utilization of magnesium resources in salt lakes. Progress in Chemistry. 2009, 21(11), 2358-2364.
Liu, H., Qing, B., Ye, X., Li, Q., Lee, K., Wu, Z., Boron adsorption by composite magnetic particles. Chemical Engineering Journal. 2009, 151(1-3), 235-240.
Liu, H., Ye, X., Li, Q., Kim, T., Qing, B., Guo, M., Ge, F., Wu, Z., Lee, K., Boron adsorption using a new boron-selective hybrid gel and the commercial resin D564. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2009, 341(1-3), 118-126.
Ye, X., Wu, Z., Li, W., Liu, H., Li, Q., Qing, B., Guo, M., Go, F., Rubidium and cesium ion adsorption by an ammonium molybdophosphate-calcium alginate composite adsorbent. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2009, 342(1-3), 76-83.
Liu, H., You, L., Ye, X., Li, W., Wu, Z., Adsorption kinetics of an organic dye by wet hybrid gel monoliths. Journal of Sol-Gel Science and Technology. 2008, 45(3), 279-290.
Ye, X., Liu, T., Li, Q., Liu, H., Wu, Z., Comparison of strontium and calcium adsorption onto composite magnetic particles derived from Fe3O4 and bis(trimethoxysilylpropyl)amine. Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2008, 330(1), 21-27.
2.专利
一种锂云母提锂尾液中铷和铯的分离提取方法, ZL.2021105483427, 2024.06.25.
一种用于硼分离的浮选剂的制备方法及浮选剂, ZL.202110567741.8, 2024.05.14
用于阴离子吸附剂的造粒剂及制备方法、阴离子吸附剂, ZL.202211019765.0, 2024.04.19
一种杂多酸盐功能化MOF基铷、铯吸附剂的制备方法, ZL.202110887970.8, 2024.03.08.
一种用于液体锂资源提取的碳基吸附剂颗粒、制备方法及制备装置, ZL.202111124046.0, 2023.09.22.
一种用于液体锂资源提取的碳基锂吸附电极的制备方法, ZL.202111124050.7, 2023.09.22.
一种球形组合锂吸附剂及其造粒方法, ZL.202211533010.2, 2023.06.02.
一种用于液体锂资源提取的铝系吸附剂颗粒制备方法, ZL.202011340822.6, 2023.05.23.
一种高强磷硅酸镁水泥及其制备方法, ZL.202111671118.3, 2023.03.24.
棒点结构的超疏水微-纳粒子、超疏水涂层液及超疏水防腐涂层的制备方法, ZL.202110313556.6, 2022.08.23.
一种用于液体铷铯资源提取的杂多酸盐离子筛吸附剂颗粒制备方法, ZL.202011346003.2, 2022.06.10.
一种用于液体铷铯资源提取的金属铁氰化物吸附剂颗粒制备方法, ZL.202011340808.6, 2022.06.10.
一种碘离子吸附剂、其制备方法及应用, ZL.201710155686.5, 2021.03.02.
分离硼的方法, ZL.201710743762.4, 2019.11.22.
一种微孔铝盐锂吸附剂及其制备方法、填料和富集锂离子的方法, ZL.201610395365.8, 2019.06.18.
铝锂中间合金的制备方法, ZL.201710034150.8, 2018.12.04.
氯离子吸附凝胶、其应用及其吸附氯离子后的再生方法, ZL.201510677681.X, 2018.03.20.
一种熔盐电解法制备单质金属或合金的启炉方法, ZL.201510802627.3, 2017.12.12.
一种从酸性卤水中提取铷铯的方法, ZL.201510703793.8, 2017.12.12.
一种离子色谱用除氯预处理柱中填充物及其制备与再生方法, ZL.201510528914.X, 2017.10.03.
一种同时测定镁和锌含量的方法及其应用, ZL.201410077613.5, 2017.07.14.
熔盐电解法制备镁‑锌中间合金的方法, ZL.201410079494.7, 2017.02.01.
硼锶离子吸附剂、其制备及应用, ZL.201410085514.1, 2016.08.31.
一种吸附分离系统, ZL.201410077210.0, 2016.06.22.
凝胶球型铯离子吸附剂、其制备方法及应用, ZL.201410015386.3, 2016.01.20.
缓释剂及其制备方法和应用, ZL.201310574687.5, 2016.01.20.
一种同时测定溴离子和碘离子的方法, ZL.201310557924.7, 2016.01.20.
从混合盐溶液提取锶的方法, ZL.201410063451.X, 2015.04.15.
凝胶球型铷/铯离子吸附剂、其制备方法及应用, ZL.201310142900.5, 2015.03.25.
有机胺类碘离子吸附剂、其制备方法及应用, ZL.201310014484.0, 2015.02.18.
凝胶型碘离子吸附剂、其制备方法及应用, ZL.201310014592.8, 2014.12.24.
利用含碘卤水制备碘化银的方法, ZL.201310014822.0, 2014.09.17.
熔盐电解产生含氯气体的吸收方法, ZL.201110140778.9, 2013.05.15.
亚甲基蓝分光法测定阴离子表面活性物质含量的方法, ZL.200910021884.8, 2012.08.15.
溴百里香酚蓝分光法测定阳离子表面活性物质含量的方法, ZL.200910021881.4, 2012.07.04.
非乳化法制备过氧化镁的方法, ZL.200910117403.3, 2012.05.23.
熔盐电解法制备镁稀土合金的方法, ZL.200910117402.9, 2011.12.21.
双波长分光光度法测定水乳浊液中烈香杜鹃油含量的方法, ZL.200910021880.X, 2011.06.22.
球形、放射状碳酸镁及其制备方法, ZL.200910117404.8, 2011.05.25.
3. 获奖荣誉