一、课题组名称: 溶液结构与界面课题组
二、课题组简介
中国科学院青海盐湖研究所溶液结构与界面课题组专注于溶液结构与动力学研究30年。课题组现为一个非常活跃和年轻的研究小组,小组成员平均年龄不到33岁。主要研究方向为通过X射线/中子散射(XRS/NS)、X射线吸收谱(XAFS)、准弹性中子散射(QENS)、密度泛函(DFT)和分子动力学(MD)等方法研究无序材料(液体或非晶体)的结构与动力学;近年来研究重点逐渐涉及固-液、液-液界面相互作用,研究将阐释浓盐溶液结晶与相变过程,为水合盐相变储能/储热材料的优化提供指导;明晰盐卤离子辨识分离的分子机制,为在分子水平上设计盐湖高值元素分离新材料提供参考。
溶液结构及界面科学是一个极富挑战的研究领域。课题组长期与日本、英国、法国和瑞典等国的研究人员保持着长期稳定的合作关系,在2019年成功举办了IUPAC第36届国际溶液化学会议,并协办了2021年环太平洋化学大会,题为"Frontiers of Molecular Approaches to Properties and Functions of Liquids and Solutions"的专题研讨会。作为中科院盐湖资源综合高效利用重点实验室和青海省盐湖资源化学重点实验室的一个研究小组。课题组热忱欢迎广大硕士、博士研究生和青年科技工作者前来访问和加盟。
三、课题组组长
周永全,1984年生,博士,研究员,博士生导师。2014年获中国科学院大学无机化学博士学位,2015年获日本科学技术振兴会“樱花科学”计划支持,在日本福冈大学山口敏男教授研究组开展合作研究。2016年-2017年获CSC公派留学计划资助继续在该研究组做访问学者。周永全研究员长期从事溶液结构、动力学及其微尺度界面相互作用的实验观测与计算机模拟研究,先后主持国家、省部级及横向项目20余项,研究成果在JPCL、PCCP、JPCB等期刊上发表SCI论文80余篇,登记软件著作权1件。现任国际溶液化学大会(IUPAC-ICSC)国际指导委员会(ISC)委员、中国化学会热力学与热分析专业委员会委员、中国化工学会无机酸碱盐智库专家, 《盐湖研究》编委、《计算机与应用化学》青年编委及《Journal of Molecular Liquids》客座编辑。青海省自然科学与工程技术学科带头人(2018),入选中国科学院人才计划项目(2018),中国科学院青年创新促进会会员(2017)。获青海省自然科学奖三等奖(第一,2022),中国化学会“青年化学家元素周期表”元素代言人(2019),AIE“关键学术论文奖”(2018),连续获得青海省自然科学优秀学术论文奖3次(2018,2016,2014)等。
电话(Tel):13997296727
邮编(P.C.):810008
邮箱(Mail):yongqzhou@isl.ac.cn
地址(Add):青海省西宁市新宁路18号
四、课题组成员
职工:山口敏男、年洪恩、朱发岩、刘红艳、柳瑞瑞、邵一凡、王啟睿、胡超
研究生:景转芳、宋露露、王云霞、柴珂珂、贾力凡、王航宇、武雅楠、赵旭
五、课题组人才专员:刘红艳
电话(Tel):15597002464
邮编(P.C.):810008
邮箱(Mail):liuhongyan198607@163.com
地址(Add):青海省西宁市新宁路18号
六、招聘信息
(1) 招聘正式职工3人
(2) 诚邀加盟申报海外优青项目
(3) 课题组长期招聘博士后
专业要求:物理化学、理论与计算化学、分析化学、材料化学、晶体学等,有意者欢迎来组面谈考察,课题组将协助报销差旅。
七、招生信息
硕士研究生(2人/年):无机化学、材料与化工
博士研究生(1年/人):物理化学、无机化学
八、科研项目
1.“类薄膜”限域空间精准设计印迹微纳组装体及其对盐湖卤水中硼的高效吸附分离研究,国家自然科学基金区域创新发展联合基金重点项目子项目,编号U22A20413, 2023.01-2026.12, 80万。
2.非晶材料结构X射线散射实验平台,青海省创新平台建设项目,编号2022-ZJ-T03, 2022.01-2024.12, 80万。
3.浓缩盐溶液在纳米或亚纳米通道中的结构、输运和界面相互作用,中科院青海盐湖研究所基础研究青年创新交叉团队基金, 2022.01-2024.12, 100万。
4.溶液的结构与动力学,青海省昆仑英才,高端创新创业人才-领军人才, 2021.10-2024.10, 60万。
5.盐湖特色含硼非晶材料的制备、性能及结构研究,青海省科技国际合作专项,2020.1.1-2022.12.31, 50万。
6.受限盐水溶液的结构与相变行为,国家自然科学基金项目,编号21973106, 2020.01-2023.12, 78万。
7.NaBH4溶液中的二氢键和储放氢,中国科学院西轻所,No.Y910041014, 2019.01- 2022.12, 52万。
8.纳米复合相变材料的储热和释放机制及熔盐的微观结构,青海省应用型基础研究项目,No.2019-ZJ-7037, 2019.1-2021.12, 40万;
9.铷铯在盐湖卤水及典型萃取体系中的局部结构,青海省应用型基础研究项目,编号:2019-ZJ-7001, 2019.01-2021.12, 40万;
10.非晶态体系的结构研究,中国科学院青年创新促进会,No.2017467, 2017.01-2020.12, 80万;
11.硫酸钠基低共晶相变储能系统的性能与微观结构,青海省自然科学基金,No.2017467, 2018.01-2020.12, 20万;
12.硫酸盐/氯化物型盐湖卤水中硼酸盐物种的分布规律和结构研究, 自然科学基金联合项目, U1607106, 2017.01-2019.12, 58万.
13.硼氢化钠碱性水溶液储放氢体系微观结构的精细解析, 国家自然科学基金青年基金项目, No.21503251, 2016.1-2018.12, 25万.
九、代表性科研成果
(一) 论文及论著
1.F.Y. Zhu, D. T. Bowron, S.G?rtner, C. H. Fang, Y.Q. Zhou, H.Y. Liu, A. C. Hannon, Structural analysis of potassium borate solutions. Physical Chemistry Chemical Physics, 2023, 25, 12207-12219.
2.J.S. Li, L.L. Sheng, Q.Y Wang, Y.X. Wang, L.L. Song, Y.Q. Zhou, F.Y. Zhu, Study on ionic association behavior in sodium nitrate solution. Spectrochimica Acta Part A, 2023, 285, 121888.
3.H.E. Gu, Y.Q. Ma, Z.K. Peng, F.Y. Zhu, X.H. Ma, Influence of polyborate ions on the fractionation of B isotopes during calcite deposition. Chemical Geology, 2023, 622, 121387.
4.P.T. Fang, X.M. Lu, Q. Zhou, D.X. Yan, J.Y. Xin, J.L. Xu, C.Y. Shi, Y.Q. Zhou, S.Q. Xia, Controlled alcoholysis of PET to obtain oligomers for the preparation of PET-PLA copolymer. Chemical Engineering Journal, 2023, 451, 138988.
5.K.K. Chai, Y.Q. Zhou, X.M. Lu, T. Yamaguchi, K. Ohara, H.Y. Liu, F.Y. Zhu, Structure of choline chloride-carboxylic acid deep eutectic solvents by wide-angle X-ray scattering and DFT calculations. Physical Chemistry Chemical Physics, 2023, 25, 10481-10494.
6.W.Q. Zhang, T. Yamaguchi, C.H. Fang, K. Yoshida, Y.Q. Zhou, F.Y. Zhu, S. Machida, T. Hattori, W. Li, Structure of an aqueous RbCl solution in the gigapascal pressure range by neutron diffraction combined with empirical potential structure refinement modeling. Journal of Molecular Liquids, 2022, 348, 118080.
7.K. Yoshida, Y. Sanada, T. Yamaguchi, M. Matsuura, H. Tamatsukuri, H. Uchiyama, The translational, rotational, and phonon dynamics of water in ZrO2/water nanofluid. Journal of Molecular Liquids, 2022, 366, 120218.
8.T. Yamaguchi, K. Yoshida, S. Machida, T. Hattori, Neutron scattering on an aqueous sodium chloride solution in the gigapascal pressure range. Journal of Molecular Liquids, 2022, 365, 120181.
9.Y.X. Xin, H.E. Nian, X. Li, B.F. Zhang, X.L. Tan, J.H. Li, Y.Q. Zhou, Construction of Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/NiCo2O4-expanded graphite multidimensional phase change material. Journal of Energy Storage, 2022, 52, 104781.
10.Y.X. Xin, H.E. Nian, J.H. Li, J.Q. Zhao, X.L. Tan, Y.Q. Zhou, F.Y. Zhu, H.Y. Liu, X. Li, Effect of NiCo2O4-modified expanded graphite on heat transfer and storage improvement of CaCl2?6H2O. Journal of Energy Storage, 2022, 46, 103902.
11.Y.X. Wang, F.Y. Zhu, T. Yamaguchi, K. Yoshida, G.G. Wang, R.R. Liu, L.L. Song, Y.Q. Zhou, H.Y. Liu, Structure of phase change energy storage material Ca(NO3)2·4H2O solution. Journal of Molecular Liquids, 2022, 356, 119010.
12.Y.X. Wang, G.G. Wang, D.T. Bowron, F.Y. Zhu, A.C. Hannon, Y.Q. Zhou, X. Liu, G.S. Shi, Unveiling the structure of aqueous magnesium nitrate solutions by combining X-ray diffraction and theoretical calculations. Physical Chemistry Chemical Physics, 2022, 24, 22939-22949.
13.Y.X. Wang, L.L. Song, G.G. Wang, H.Y. Liu, Z.F. Jing, Y.Q. Zhou, F.Y. Zhu, Y.H. Zhang, Structure analysis of aqueous Mg(NO3)2 solutions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022, 267, 120478.
14.G.G. Wang, Y.Q. Zhou, Z.F. Jing, Y.X. Wang, K.K. Chai, H.Y. Liu, F.Y. Zhu, Z.J. Wu, Anomalous ion hydration and association in confined aqueous CaCl2 solution. Journal of Molecular Liquids, 2022, 360, 119409.
15.D.Q. Shen, Y.L. Song, X.P. Chen, Y.Q. Zhou, H. Li, J.M. Pan, Fabricating ultrafine zirconium oxide based composite sorbents in “soft confined space” for efficiently removing fluoride from environmental water. Chemical Engineering Journal, 2022, 444, 136199.
16.D.K. Pang, Z.H. Zhang, Y.Q. Zhou, Z.H. Fu, Q. Li, Y.M. Zhang, G.G. Wang, Z.F. Jing, The process and mechanism for cesium and rubidium extraction with saponified 4-tert-butyl-2-(α-methylbenzyl) phenol. Chinese Journal of Chemical Engineering, 2022, 46, 31-39.
17.R.R. Liu, H.L. Zhai, H.P. Shao, T.H. Wang, Biological effect of black phosphorus nanosheets on the interaction between SARS-CoV-2 S protein and ACE2. Physical Chemistry Chemical Physics, 2022, 24, 27388-27393.
18.H.Y. Liu, Y.Q. Zhou, D. An, G.G. Wang, F.Y. Zhu, T. Yamaguchi, Structure of aqueous KNO3 solutions by wide-angle X-ray scattering and density functional theory. Journal of Physical Chemistry B, 2022, 126, 5866-5875.
19.Z.F. Jing, Y.Q. Zhou, W.Q. Zhang, T. Yamaguchi, K. Yoshida, G.G. Wang, L. Han, Structures of 18-crown-6/Cs+ complexes in aqueous solutions by wide angle X-ray scattering and density functional theory. Journal of Molecular Liquids, 2022, 360, 119477.
20.M.X. Ji, Y.F. Shao, E. Nkudede, Z.H. Liu, X. Sun, J.Z. Zhao, Z.R. Chen, S. Yin, H.M. Li, J.X. Xia, Oxygen vacancy triggering the broad-spectrum photocatalysis of bismuth oxyhalide solid solution for ciprofloxacin removal. Journal of Colloid and Interface Science, 2022, 626, 221-230.
21.X.P. Ding, J.W. Huang, F.Y. Zhu, Y.X. Wang, Y.F. Shao, X. Li, Y.Q. Zhou, L.L. Song, Study on energy storage performance of thermally enhanced composite phase change material of calcium nitrate tetrahydrate. Journal of Energy Storage, 2022, 52, 104879.
22.X.P. Chen, W.Q. Wang, Y.L. Song, Y.Q. Zhou, H. Li, J.M. Pan, Fabrication of 2D nanosheet sorbents through metastable emulsion droplets and subsequent two-step grafting polymerization for efficient blood lead removal in vitro. Journal of Hazardous Materials, 2022, 438, 129522.
23.K.K. Chai, X.M. Lu, Y.Q. Zhou, H.Y. Liu, G.G. Wang, Z.F. Jing, F.Y. Zhu, L. Han, Hydrogen bonds in aqueous choline chloride solutions by DFT calculations and X-ray scattering. Journal of Molecular Liquids, 2022, 362, 119742.
24.Y.F. Shao, M.X. Ji, Y. Zhang, J.Z. Zhao, Z.H. Liu, H.P. Li, H.M. Li, S. Yin, J.X. Xia, Integration of double halogen atoms in atomically thin bismuth bromide: Mutative electronic structure steering charge carrier migration boosted broad-spectrum photocatalysis. Applied Surface Science, 2021, 541, 148477.
25.R.R. Liu, H.L. Zhai, Y.J. Meng, M. Zhu, T. Wen, N.Z. Jin, Adsorption Behaviors of Typical Proteins on BP, GR, and C2N Surfaces. Journal of Chemical Information and Modeling, 2021, 61, 1300-1306.
26.X. Ge, J. Xu, Q.D. Hu, R. Qiu, P.S. Lai, Y.F. Han, F. Yang, Y.Q. Zhou, J.Y. Qin, P.F. Yu, W.Q. Lu, J.G. Li, inhibiting effect of heterogeneous cations aggregation enhanced by oxygen deficiency on glass formation of BaTi2O5 melts. Journal of the American Ceramic Society, 2021, 104, 6207-6226.
27.F.Y. Zhu, W.Q. Zhang, H.Y. Liu, Y.Q. Zhou, X.F. Wang, C.H. Fang, Raman and ab initio analyses of ion pairs in concentrated K[B(OH)4] droplets. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, 230, 118039.
28.F.Y. Zhu, W.Q. Zhang, H.Y. Liu, X.F. Wang, Y.Q. Zhou, C.H. Fang, Y.H. Zhang, Micro–Raman and density functional theory analyses of ion pairs in concentrated sodium tetrahydroxyborate droplets. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2020, 224, 117308.
29.F.Y. Zhu, T. Yamaguchi, K. Yoshida, W.Q. Zhang, H.Y. Liu, Y.Q. Zhou, C.H. Fang, Ion hydration and association in aqueous potassium tetrahydroxyborate solutions. Analyst, 2020, 145, 2245-2255.
30.Y.Q. Zhou, T. Yamaguchi, W.Q. Zhang, K. Ikeda, K. Yoshida, F.Y. Zhu, H.Y. Liu, The structural elucidation of aqueous H3BO3 solutions by DFT and neutron scattering studies. Physical Chemistry Chemical Physics, 2020, 22, 17160-17170.
31.Y.Q. Zhou, T. Yamaguchi, K. Ikeda, K. Yoshida, T. Otomo, C.H. Fang, W.Q. Zhang, F.Y. Zhu, Dihydrogen Bonds in Aqueous NaBD4 Solution by Neutron and X-ray Diffraction. The Journal of Physical Chemistry Letters, 2020, 11, 1622-1628.
32.R. Sakamoto, M. Yamashita, K. Nakamoto, Y.Q. Zhou, N. Yoshimoto, K. Fujii, T. Yamaguchi, A. Kitajou, S. Okada, Local structure of a highly concentrated NaClO4 aqueous solution-type electrolyte for sodium ion batteries. Physical Chemistry Chemical Physics, 2020, 22, 26452-26458.
33.Z.F. Jing, G.G. Wang, Y.Q. Zhou, D.K. Pang, F.Y. Zhu, H.Y. Liu, Selectivity of 18-crown-6 ether to alkali ions by density functional theory and molecular dynamics simulation. Journal of Molecular Liquids, 2020, 311, 113305.
34.F.Y. Zhu, H.Y. Liu, W.Q. Zhang, Y.Q. Zhou, X.F. Wang, Y.H. Zhang, C.H. Fang, Ab-initio investigation on ion–associated species and association process in Li[B(OH)4] solution. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 213, 423-429.
35.Y.Q. Zhou, T. Yamaguchi, K. Yoshida, C.H. Fang, Y. Fang, F.Y. Zhu, Structure of alkaline aqueous NaBH4 solutions by X-ray scattering and empirical potential structure refinement. Journal of Molecular Liquids, 2019, 274, 173-182.
36.Z. Liu, Y.Q. Zhou, M. Guo, B.L. Lv, Z.J. Wu, W.Z. Zhou, Experimental and theoretical investigations of Cs+ adsorption on crown ethers modified magnetic adsorbent. Journal of Hazardous Materials, 2019, 371, 712-720.
(二) 专利及软著等
1.广角X射线及中子散射数据解析软件[简称:XNSA], 登记号:2021SR0128195, 2021.
2.通过水热提纯四硼酸锂的方法, ZL.201510078259.2;
3.电催化氧化法制备氧化石墨烯的方法,ZL.201410474357.3;
4.一种质量滴定装置及带有滴定保护组件的滴定方法,ZL.201410152104.4;
5.用于液体X射线散射的样品池,ZL.201320032922.1。