镁基储氢材料课题组

发布时间:2024-10-15

一、课题组名称:镁基储氢材料课题组

二、课题组简介

1. 镁基储氢材料设计方法学

2. 镁基储氢材料吸放氢机制研究

3. 镁基储氢关键技术及示范应用

三、课题组组长

刘虎,中国科学院青海盐湖研究所研究员、博士生导师,主要研究方向聚焦于氢能领域的应用基础研究,长期致力于多尺度能源转化功能材料的设计与制备,用于制、储、运与用氢能的研究等方面,取得了一系列科研成果,发表SCI学术论文60余篇,其中包括Nature comm.、J. Am. Chem. Soc.、Adv. Mater.、Nano Lett.、Angew. Chem. Int. Ed.、Adv. Funct. Mater.、Chem. Eng. J.、J. Mater. Chem. A 等高水平论文,其中10篇入选ESI高被引论文、2篇入选ESI热点论文,H指数为26(谷歌);授权专利10项;主持与参与省部级、中国科学院级与国家级氢能项目多项。现担任《Adv. Funct. Mater.》、《J. Mater. Chem. A.》、《Chem. Eng. J.》等期刊审稿人;《稀有金属》与《Rare Metals》青年编委;中国稀土学会第七届固体科学与新材料专业委员会委员,国家自然基金委/工信部项目函评专家。

学术兼职:

Rare Metals期刊青年编委;

中国稀土学会第七届固体科学与新材料专业委员会委员;

国家自然基金委/工信部项目函评专家。

联系方式:

电话(Tel.):15289383899 

邮编(P.C.):810008 

邮箱(Mail):liuhu@isl.ac.cn 

地址(Add.):青海省西宁市新宁路18号  

四、课题组副组长:李文锋 副研究员

联系方式:

电话(Tel.):15981798628 

邮编(P.C.):810008 

邮箱(Mail):liwf@isl.ac.cn 

地址(Add.):青海省西宁市新宁路18号  

五、课题组成员

六、课题组人才专员:李文锋

联系方式:

电话(Tel.):15981798628 

邮编(P.C.):810008 

邮箱(Mail):liwf@isl.ac.cn 

地址(Add.):青海省西宁市新宁路18号  

七、招聘信息

1. 直接/柔性引进高层次人才(第一,二层次) 2-3名。 要求年龄原则上不超过45周岁,在国内外高水平大学、科研机构等取得博士学位,在盐湖战略元素相关研究领域取得了突出学术贡献,具有5年及以上科研工作经历,主持过国家级、省部级及以上科研项目的人才,或具有相当水平的高层次人才。薪酬待遇参照青海盐湖所招聘政策。  

2. 直接引进青年才俊(第三,四层次) 2-3名。 要求年龄原则上不超过35周岁,在国内外高水平大学、科研机构等取得博士学位,在盐湖战略元素相关研究领域取得了突出学术贡献。薪酬待遇参照青海盐湖所招聘政策。  

八、招生信息

课题组每学年招收博士研究生2名,硕士研究生2-4名。 

研究方向:镁基储氢材料设计方法学,镁基储氢材料吸放氢机制研究,镁基储氢关键技术及示范产业。

专业要求:无机化学、物理化学、材料与化工、材料物理与化学、化学工艺、化学工程、材料科学与工程、理论计算,以及符合研究方向要求的相关专业。

热忱欢迎有志学子到中国科学院青海盐湖研究所镁基储氢材料课题组攻读学位!

九、课题组科研成果

1. 本课题组成员主持及参与各类科研项目如下:

[1] 中国科学院引进人才青年项目, Mg-Ni基功能材料的设计与制备及其储氢应用研究,2024-04至2027-04,300万元,主持。

[2] 国家自然科学基金委员会,面上项目,非贵金属单原子-曲面氮杂素馨烯组装材料的催化产氢机理研究,2023-01-01 至 2026-12-31,54万元,主持。

[3] 陕西省面上基金,Pd修饰Co@Ag核壳纳米线界面调控及其光催化还原硝酸根机理,基金号:2021JM-356, 4万,主持。

[4] 陕西省技术创新引导专项基金,高效甲酸在线制氢\加氢一体化装备研究,陕2023-01至2024-12,100万元。

[5] 陕西省技术创新引导专项基金(以演带评),高效甲酸在线制氢\加氢一体化装备研究,陕2024-01至2024-12,50万元,主持。
[6] 中共陕西省委,陕西省“三秦学者”创全国一流团队,2021-01至 2023-12,200万。
[7] 陕西省科技厅,陕西省创新团队,2021-01至 2023-12,50万元。

[8] 陕西省技术创新引导专项基金,用于提取Sr的固相吸附材料合成及性能测试,2022-12至2023-12,46.83万元。

[9] 国家自然科学基金委员会,面上项目,干旱区农田土壤中地膜微塑料的环境效应, 2025.01-2028.12,47万元,主持。

[10] 国家自然科学基金委员会,青年基金,新疆农田土壤中微塑料分离方法优化及其来源、分布和污染特征研究,2020.01-2023.01,27万元,主持。

[11] 中科院西部博士 B 类资助项目,改性玉米秸秆生物炭对持久性有机物污染物(POPs)处理技术研究,2016.06-2019.06,40万元,主持。

[12] 新疆维吾尔自治区重点研发专项,秸秆和禽畜粪便蒸汽爆破碳化制水热碳技术研究,2022.10-2026.10,550万元。

[13] 新疆维吾尔自治区重点研发专项,人工湿地污水资源化处理关键技术研究与示范,2017.06-2021.12,330万元。

[14] 新疆维吾尔自治区自然基金面上项目,地膜源微塑料纵向迁移机制及影响因素研究,2022.10-2025.10,10万元,主持。

[15] 新疆维吾尔自治区自然基金面上项目,新疆农田土壤中微塑料分离提取及污染特性研究,2018.06-2021.06,7 万元,主持。

[16] 新疆维吾尔自治区重点实验室开放课题,棉花秸秆生物炭强化人工湿地污水处理技术,2016.07-2019.07,20 万元,主持。

2. 本课题组成员发表学术论文如下:

[1] Hu Liu*, Xueqian Li, Xiaoying Zhao, Min Zhang, Xinhua Liu, Shichun Yang, Hongjing Wu*, and ZhenhuiMa*. Large Annular Dipoles Bounded between Single-Atom Co and Co Cluster for Clarifying Electromagnetic Wave Absorbing Mechanism. Adv. Funct. Mater. 2023, 2304442.

[2] Hu Liu*, Rongrong Jia, Chuanjian Qin, Qin Yang, Zuobin.Tang, Menggang Li*, Zhenhui. Ma*. Anti-COPoisoning FePtRh Nanoflowers with Rh-Rich Core and Fe-Rich Shell Boost Methanol Oxidatio Electrocatalysis. Adv. Funct. Mater. 2022, 2210626.

[3] Hu Liu*, Qian Lei, Ruoyan.Miao, Mingzi.Sun, Chuanjian Qin, Liang Zhang, Gan Ye, YaoYao*, Bolong Huang*, Zhenhui Ma*. Asymmetric Coordination of Single-Atom Co Sites Achieves Efficien Dehydrogenation Catalysis. Adv. Funct. Mater. 2022, 2207408.

[4] Guanghui Han#, Menggang Li#, Hu Liu#, Weiyu Zhang, Lin He, Fenyang Tian, Yequ Liu, Yongsheng Yu*, Weiwei Yang*, Shaojun Guo*. Short-Range Diffusion Enables General Synthesis of Medium-Entropy Alloy Aerogels. Adv. Mater. 2022, 2202943.

[5] Hu Liu, Xuexiang Li, Zhenhui Ma, Mingzi Sun, Menggang Li, Zhenyu Zhang, Liang Zhang, Zuobi Tang, Yao Yao, Bolong. Huang, and Shaojun Guo. Atomically Dispersed Cu Catalyst for Efficien Chemoselective Hydrogenation Reaction. Nano Lett. 2021, 21, 10284-10291.

[6] Meng.qi Shen#, Hu Liu#, Chao Yu, Zhouyang Yin, Michelle Muzzio, Junrui Li, Zheng Xi, Yongsheng Yu*, Shouheng Sun*. Room-Temperature Chemoselective Reduction of 3-Nitrostyrene to 3-Vinylaniline by Ammonia Borane over Cu Nanoparticles. J. Am. Chem. Soc. 2018, 140, 16460-16463.

[7] Lingjun Pei, Shaolei Xie, Hui Guo, Xueqian Li, Huidong Xie, Zuobin Tang, Guanghui Han, Zhonghong Xia*, Menggang Li*, Hu Liu*. Ultrathin porous PdPtNi nanosheets as efficient electrocatalysts for alcohol oxidation reactions. Chem. Eng. J. 2024, 483, 149113.

[8] Qian Lei, Ruoyan Miao, Xueqian Li, Xiaoyu Liu, Yuanyuan Li, Zhangwei He, Huidong Xie, Fang Song, Xiang Liu*, Hu Liu*. Efficient hydrogen production from formic acid over Ag@ AgPd nanotriangulars at room temperature. Fuel 2023, 355, 129539.

[9] Zhenhui Ma, Hu Liu, Zhikun Luo, A General Method for the Large‐Scale Preparation of Multifunctional Magnetic Sm-Fe/Co Nanomaterials, Adv. Funct. Mater. 2023, 2301350.

[10] Hu Liu*, Xuexiang Li, Xinyang Liu, Zhenhui. Ma, Zhouyang Yin, Weiwei Yang, Yongsheng Yu.* Schiff-base-rich g-CxN4 supported PdAg nanowires as an efficient Mott–Schottky catalyst boosting photocatalytic dehydrogenation of formic acid. Rare Metals 2021, 40, 808-816.

[11] Ruoyan Miao, Hu Liu*, Qian Lei, Lvling Zhong, Liang Zhang, Jianzheng He, Zhenhui Ma, Yao Yao. Single-organic component g-C3.6N4 achieves superior photoactivity antibacterial. Chem. Eng. J. 2022, 440, 135873.

[12] Hu Liu, Bolong Huang, Jinhui Zhou, Kai Wang, Yongsheng Yu, Weiwei Yang, Shaojun Guo. Enhanced electron transfer and light absorption on imino polymer capped PdAg nanowire networks for efficient room-temperature dehydrogenation of formic acid. J. Mater. Chem. A 2018, 6, 1979-1984.

[13] Hu Liu, Yong Guo, Yongsheng Yu, Weiwei Yang, Mengqi Shen, Xinyang Liu, Shuo Geng, Junrui Li, Chao Yu, Zhouyang Yin, Haibo Li. Surface Pd-rich PdAg nanowires as highly efficient catalysts for dehydrogenation of formic acid and subsequent hydrogenation of adiponitrile. J. Mater. Chem. A 2018, 6, 17323-17328.

[14] Hu Liu, Xinyang Liu, Yongsheng Yu, Weiwei Yang, Ji Li, Ming Feng, Haibo Li. Bifunctional networked Ag/AgPd core/shell nanowires for the highly efficient dehydrogenation of formic acid and subsequent reduction of nitrate and nitrite in water. J. Mater. Chem. A 2018, 6, 4611-4616.

[15] Hu Liu, Yongsheng Yu, Weiwei Yang, Wenjuan Lei, Manyi Gao, Shaojun Guo. High-density defects on PdAg nanowire networks as catalytic hot spots for efficient dehydrogenation of formic acid and reduction of nitrate. Nanoscale 2017, 9, 9305-9309.

[16] Hu Liu, Xinyang Liu, Weiwei Yang, Mengqi Shen, Shuo Geng, Chao Yu, Bo Shen, Yongsheng Yu. Photocatalytic dehydrogenation of formic acid promoted by a superior PdAg@g-C3N4 Mott–Schottky heterojunction. J. Mater. Chem. A 2019, 7, 2022-2026.

[17] Zhenhui Ma, Hu Liu, Ming Yue. Magnetically recyclable Sm2Co17/Cu catalyst to chemoselectively reduce the 3-nitrostyrene into 3-vinylaniline under room temperature. Nano Res. 2019, 12, 3085-3088.

[18] Zhenhui Ma, Ming Yue, Hu Liu, Zhouyang Yin, Kecheng Wei, Huaqin Guan, Honghong Lin, Mengqi Shen, Shizhong An, Qiong Wu, Shouheng. Sun. Stabilizing Hard Magnetic SmCo5 Nanoparticles by N-Doped Graphitic Carbon Layer. J. Am. Chem. Soc. 2020, 142, 18, 8440-8446.

[19] Shuo Geng, Hu Liu, Weiwei Yang, Yongsheng Yu. Activating the MoS2 Basal Plane by Controllable Fabrication of Pores for an Enhanced Hydrogen Evolution Reaction. Chem. Eur. J. 2018, 71, 19075-19080.

[20] Bo. Shen, Chao. Yu, Alexander. A. Baker, Scott. K. McCall, Yong. Sheng. Yu, Dong. Su, Zhou. Yang. Yin, Hu. Liu, Jun. Rui. Li, Shou. Heng. Sun. Chemical Synthesis of Magnetically Hard and Strong Rare Earth Metal Based Nanomagnets. Angew. Chem. Int. Ed. 2019, 58, 602-606.

[21] Zhouyang Yin, Chao Yu, Zhonglong Zhao, Xuefeng. Guo, Mengqi Shen, Na Li, Michelle Muzzio, Junrui Li, Hu Liu, Honghong Lin, Jie Yin, Gang Lu, Dong Su, Shouheng Sun. Cu3N Nanocubes for Selective Electrochemical Reduction of CO2 to Ethylene. Nano Lett. 2020, 19, 8658-8663.

[22] Xin Zhang, Weiwei Yang, Manyi Gao, Hu Liu*, Kefei Li, Yongsheng Yu*. Room-temperature solid phase surface engineering of BiOI sheets stacking g-C3N4 boosts photocatalytic reduction of Cr(VI). Green Energy & Environ. 2020. 7, 66-74.

[23] Hu Liu, Mengqi Shen, Peng Zhou, Zhi Guo, Xinyang Liu, Weiwei Yang, Manyi Gao, Min Chen, Huanqin Guan, Nitin P. Padture, Yongsheng Yu, Shaojun Guo, Shouheng Sun. Linking melem with conjugated Schiff-base bonds to boost photocatalytic efficiency of carbon nitride for overall water splitting. Nanoscale 2021. 13, 9315-9321.

[24] Xinyang Liu, Hu Liu*, Yingjun Wang, Weiwei Yang*, Yongsheng Yu*. Nitrogen-rich g-C3N4@AgPd Mott-Schottky heterojunction boosts photocatalytic hydrogen production from water and tandem reduction of NO3− and NO2−. J. Colloid Interface Sci. 2021, 581, 619-626.

[25] Li, W F, Wufuer R, Duo, J, Wang, S Z, Luo, Y M , Zhang, D Y , Pan, X L*; Microplastics in agricultural soils: Extraction and characterization after different periods of polythene film mulching in an arid region, Science of the Total Environment, 2020, 749, 141420.

[26] Meng, Y T, Li, W F, Pan, X L*, Gadd, G M, Applications of nanozymes in the environment, Environmental Science: Nano, 2020, 7, 1305.

[27] Li, W F, Wang, S Z, Wufuer R, Duo, J, Pan, X L*, Distinct soil   microplastic distributions under various farmland-use types around Urumqi, China, Science of The Total Environment, 2023, 857, 159573.

[28] Liu, B S, Li, W F, Pan, X L*, Zhang, D Y, The persistently breaking trade-offs of three-decade plastic film mulching: Microplastic pollution, soil degradation and reduced cotton yield, Journal of Hazardous Materials, 2022, 439, 129586.

3. 本课题组成员授权专利如下:

[1] 刘虎, 郭珲, 赵刘会, 王斌. 一种还原硝酸根的水处理装置. 授权日: 2024/06/14, 授权号: ZL202322997438.9.

[2] 刘虎, 陈双莉, 孙小琴. 一种单原子铜催化剂及其克级制备方法和选择性还原功能有机分子的应用. 授权日: 2022/09/27, 授权号: ZL202010851198.X.

[3] 刘虎, 陈双莉, 孙小琴. 一种纳米线网络结构的铜基催化剂及其制备方法和应用. 授权日: 2022/11/04, 授权号: ZL202010819388.3.

[4] 刘虎, 苗若岩, 张良. 一种席夫碱扩大共轭性的氮化碳伤口敷料及其制备方法. 授权日: 2022/08/02, 授权号: ZL202110790619.7.

[5] 刘虎, 苗若岩, 张良. 一种纳米高熵氧化物气凝胶及其制备方法. 授权日:2023/04/21, 授权号: ZL202210096551.7.

[6] 于永生,刘虎,杨微微. 一种聚乙烯吡洛烷亚胺高分子化合物及其制备方法和应用. 授权号:ZL201610971419.0.

[7] 于永生,刘虎,杨微微. 一种具有褶皱状石墨相氮化碳的制备方法及其应用. 授权号:ZL201710704599.0.

[8] 李文锋,潘响亮,宋文娟,张道勇. 基于高剪切乳化分散的农田土壤聚乙烯微塑料分离方法, 授权号:ZL201710613805.7.

[9] 李文锋,多佳,裴亮,杨帆,热合曼江·吾甫尔,膜下滴灌模式土壤中地膜微塑料纵向迁移扩散的模拟装置,授权号:ZL20232 2141181.7.

4.本课题组成员获奖情况如下:

[1] 中国发明协会发明创业创新奖 一等奖

[2] 中国技术市场协会金桥奖 二等奖

[3] Rare Metals 优秀学术论文奖。

[4] 全国大学生互联网+,省级银奖(第一指导教师,连续两届获奖)。


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